SYNTHESIS AND CHARACTERIZATION OF Co(II), Ni(II) AND Cu(II) COMPLEXES WITH 2-[-(4- BROMOBENZYLIDENE)HYDRAZINYLIDENE]-1, 2-DIPHENYLETHANIMINE
Main Article Content
Abstract
New Schiff base ligand 2-[-(4-bromobenzylidene) hydrazinylidene]-1,2-diphenylethanimine was synthesized via condensation of α-benzilmonoximehydrazone and 4-bromobenzaldehyde in ethanol. Complexes were obtained from 1:2 molar ratio reactions with metal ions and ligand, 2NA on reaction with MCl 2.nH2O salt yields complexes corresponding to the formulas [M(L)2 ],where M = Co(II), Ni(II) and Cu(II). The 1H-NMR, FT-IR, electronic absorption spectra and elemental analysis were used for the characterization of the ligand. The geometry of complexes elucidated by FT-IR, electronic absorption spectra, conductance, and magnetic susceptibility measurements. All complexes are non-electrolytes in nitrobenzene solution. Octahedral geometries have been suggested for each of the complexes. The ligand is bidentate and leads to deprotonation coordination.
Downloads
Download data is not yet available.
Article Details
How to Cite
Yadav, P., Badekar, R., Jain, K., & Lokhande, R. (2021). SYNTHESIS AND CHARACTERIZATION OF Co(II), Ni(II) AND Cu(II) COMPLEXES WITH 2-[-(4- BROMOBENZYLIDENE)HYDRAZINYLIDENE]-1, 2-DIPHENYLETHANIMINE . Journal of Advanced Scientific Research, 12(01 Suppl 1), 287-294. https://doi.org/35
Section
Research Article
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.