Synthesis of Fe3O4-Ag core shell nanoparticles using Cinnamomum verum bark extract and removal of methyl orange from aqueous media
Main Article Content
Abstract
Green synthesis of Fe3O4-Ag core shell nanoparticles (CSNPs) was performed using Cinnamomum verum bark extract (CVBE) as the green solvent, reducing agent and capping agent. Aqueous solutions of AgNO3, FeCl3.6H20 and CH3COONa were used for the synthesis. The first formation of Fe3O4-Ag CSNPs was observed within 10 minutes of the reaction time. The result recorded from UV-Vis spectroscopy, Fourier Transform infrared spectroscopy (FTIR) and Energy dispersive spectroscopy (EDS) favours the biosynthesis and characterization of Fe3O4-Ag CSNPs. Scanning electron microscopy (SEM) reveals that the shape is nearly spherical and Transmission electron microscopy (TEM) confirms the shape as spherical and minimum size achieved is 19 nm. The capability of synthesised Fe3O4-Ag CSNPs for adsorption of methyl orange (MO) was tested in batches. It was observed that the process is pH dependent with maximum adsorption occurring at pH 6. The adsorption equilibrium was achieved after 120 min of contact time. The data observed was fitted one by one to three different isotherm models, viz., Langmuir, Freundlich and Temkin isotherm model to find the mode of adsorption. The process was best described by Langmuir isotherm. The adsorption kinetics was further analysed by using the pseudo-first-order, pseudo-second-order and the Weber-Morris diffusion model on adsorption data. The kinetic data of this adsorption obeyed pseudo-second-order rate equation.
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Kumari, D. P., & Alam, P. M. (2023). Synthesis of Fe3O4-Ag core shell nanoparticles using Cinnamomum verum bark extract and removal of methyl orange from aqueous media. Journal of Advanced Scientific Research, 14(04), 41-50. https://doi.org/10.55218/JASR.202314407
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Research Article
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References
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4 Kuo-Cheng Chen, J. Wu, C. Huang, Y. Liang, S. J. Hwang, Decolorization of azo dye using PVA-immobilized microorganisms, J. of Biotech. 101 (2003) 241-252.
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6 Vinod K. Gupta, R. Jain, S. Varshney, Removal of Reacto fix golden yellow 3 RFN from aqueous solution using wheat husk—An agricultural waste, J. of Hazar. Mat. 142 (2007) 443-448.
7 Vinod K. Gupta, I. Ali, V. K. Saini, Adsorption studies on the removal of Vertigo Blue 49 and Orange DNA13 from aqueous solutions using carbon slurry developed from a waste material, J. of Col. and Interface Sci. 315 (2007) 87-93.
8 V. K. Gupta, A. Mittal, V. Gajbe, J. Mittal, Adsorption of basic fuchsin using waste materials—bottom ash and deoiled soya—as adsorbents, J.of Col. and Interface Sci. 319 (2008) 30-39.
9 N. P. Cheremisinoff, Handbook of Water and Wastewater Treatment Technologies, Butterworth-Heinemann, Boston, 2002.
10 O. Marmagne, C. Coste, Color removal from textile plant effluents, Am. Dyestuff Rep. 85 (1996) 15–20.
11 Shi, B.Y., Li, G.H., Wang, D.S., Feng, C.H., Tang, H.X., Removal of direct dyes by coagulation: the performance of preformed polymeric aluminum species. J. Hazard. Mater. 143 (2007) 567–574.
12 Wang, M., Li, H., Wu, J., Huo, Y., Guo, G., Cao, F., Flocculant for purification of printing and dyeing wastewater. Univ Shanghai Normal 2006.
13 Zhou, Y., Liang, Z., Wang, Y., Decolorization and COD removal of secondary yeast wastewater effluents by coagulation using aluminium sulphate, Desalination 225 (2008) 301–311.
14 Gupta, V.K., Jain, R., Varshney, S., Electrochemical removal of the hazardousdye Reactofix Red 3 BFN from industrial effluents. J. Colloid Interface Sci. 312, 2007, 292–296
15 Lin, S.H., Peng, C.F., Treatment of textile wastewater by electrochemical method, Water Res. 28 (1994) 277–282.
16 V. K. Gupta, A. Mittal, V. Gajbe, Adsorption and desorption studies of a water soluble dye, Quinoline Yellow, using waste materials, J. of Col. and Interface Sci. 284 (2005) 89-98.
17 Bansal, R.C., Goyal, M., Activated Carbon Adsorption, Taylor & Francis Group, Boca Raton, 2005.
18 Danis, T.G., Albanis, T.A., Petrakis, D.E., Pomonis, P.J., Removal of chlorinated phenols from aqueous solutions by adsorption on alumina pillared clays and mesoporous alumina aluminum phosphates, Water Res. 32 (1998) 295–302.
19 Freeman, H.M., Standard Handbook of Hazardous Waste Treatment and Disposal, second ed. McGraw-Hill, New York, 1989.
20 K. Imamura, E. Ikeda, T. Nagayasu, T. Sakiyama, K. Nakanishi, Adsorption behavior of methylene blue and its congeners on a stainless steel surface, J. Colloid Interface Sci. 245 (2002) 50–57.
21 A. I. Liapis, Fundamentals of Adsorption. Engineering Foundation, New York, 1987.
22 C. L. Mantell, In: Adsorption, second ed. McGraw-Hill Book Company, Inc., New York, 1951.
23 J. S. Mattson, H.B.J. Mark, Activated Carbon Surface Chemistry and Adsorption from Solution. Marcel Dekker, Inc., New York, 1971.
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25 F. Quignon, F. Thomas, C. Gantzer, A. Huyard, L. Schwartzbrod, Virus adsorption in a complex system: an experimentally designed study, Water Res. 32 (1998) 1222–1230.
26 Weber Jr., W.J., Hopkins, C.B., Bloom Jr., R., Physicochemical treatment of wastewater, J. Water Pollut. Control Fed. 42 (1970) 83–89.
27 Palaniselvam Kuppusamy, M. M. Yusoff, G. P. Maniam, N. Govindan, Biosynthesis of metallic nanoparticles using plant derivatives and their new avenues in pharmacological applications – An updated report, Saudi Pharmaceutical Journal 24 (2016) 473–484.
28 Dapeng Chen, X. Qiao, X. Qiu, J. Chen, Synthesis and electrical properties of uniform silver nanoparticles for electronic applications, J. Mate. Sci. 44 (2009) 1076–1081.
29 Hongbo Wang, Q. Wei, X. Wang, W. Gao, X. Zhao, Antibacterial properties of PLA nonwoven medical dressings coated with nanostructured silver, Fibers and Polymers 9(2008) 556–560.
30 Lee Kim, K. Jun, W. S. Sung, S. Moon, J. Choi, J. G. Kim ,Antifungal Effect of Silver Nanoparticles on Dermatophytes and Dong Gun, J. Microbiol. Biotechnol. 18 (2008) 1482–1484.
31 H.J. Lee, S.Y. Yeo, S.H. Jeong, Antibacterial effect of nanosized silver colloidal solution on textile fabrics, J. Mater. Sci. 38 (2003) 2199-2204.
32 G. Lakshmanan, A. Sathiyaseelan, P. T. Kalaichelvan, K. Murugesan, Plant-mediated synthesis of silver nanoparticles using fruit extract of Cleome viscosa L.: Assessment of their antibacterial and anticancer Activity, Karbala International J. of Modern Sci. 4 (2018) 61-68.
33 V.V. Makarov, A.J. Love, O.V. Sinitsyna, S.S. Makarova, I.V. Yaminsky, M.E. Taliansky, N.O. Kalinina, Green nanotechnologies: synthesis of metal nanoparticles using plants, Acta Naturae 6 (1) (2014) 35-44.
34 Siavash Iravani, Green synthesis of metal nanoparticles using plants, Green Chem. 13 (2011) 2638-2650.
35 N. Cotolan, M. Rak, M. Bele, A. Cör, L.M. Muresan, and I. Milošev, “Sol-gel synthesis, characterization and properties of TiO2 and Ag-TiO2 coatings on titanium substrate,” Surf. & Coatings Technol., 307 (2016) 790–799.
36 C. Gutierrez-Wing, R. Esparza, C. Vargas-Hernandez, M.E.F. Garciaand M. Jose- Yacaman, “Microwave-assisted synthesis of goldnanoparticles self-assembled into self-supported superstructures,” Nanoscale 4 (2012) 2281–2287.
37 M.H. Magnusson, K. Deppert, J.O. Malm, J.O. Bovin, and L. Samuelson, “Size selected gold nanoparticles by aerosol technology,” Nanostruct. Mater., 12 (1999) 45-48.
38 J. Zhu, J. Shi, Y. Pan, X. Liu, and L. Zhou, “Synthesis of uniform silver nanoparticles by a microwave method in polyethylene glycol with the assistant of polyvinyl pyrrolidone,” J. Nat. Sci., 18 (2013) 530–534.
39 Thomas R, Nair AP, Kr S, Mathew J, Ek R. Antibacterial activity and synergistic effect of biosynthesized AgNPs with antibiotics against multidrug-resistant biofilm-forming coagulase-negative staphylococci isolated from clinical samples, Appl Biochem Biotechnol 173 (2014) 449-60.
40 Kumar PPNV, Pammi SVN, Kollu P, Satyanarayana KVV, Shameem U. Green synthesis and characterization of silver nanoparticles using Boerhaavia diffusa plant extract and their antibacterial activity. Ind Crops Prod 52 (2014) 562-6.
41 Matthew M. Zuckerman, Alan H. Molof and Walter J. Weber, High Quality Reuse Water by Chemical-Physical Wastewater Treatment [with Discussion] Jr. Journal (Water Pollution Control Federation) 42 (1970) 437-463.
42 M. G. Guzman, J. Dille, S. Godet, Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity. Int J Chem Biomol Eng 2 (2009) 104-11.
43 X. Fei, M. Jia, X. Du, Y. Yang, R. Zhang, Z. Shao, X. Zhao, X. Chen, Green synthesis of silk fibroin-silver nanoparticle composites with effective antibacterial and biofilm-disrupting properties, Biomacromolecules 14 (2013) 4483–4488.
44 Ales Panacek, M. Kolar, R. Vecerova, R. Prucek, J. Soukupova, V. Krystof, P. Hamal, R. Zboril, L. Kvitek, Antifungal activity of silver nanoparticles against Candida spp., Biomaterials 30 (2009) 6333-6340.
45 Christoph Seger, M. Godejohann, L. Tseng, M. Spraul, A. Girtler, S. Sturm, H. Stuppner, LC-DAD-MS/SPE-NMR Hyphenation. A Tool for the Analysis of harmaceutically Used Plant Extracts: Identification of Isobaric Iridoid Glycoside Regioisomers from Harpagophytum procumbens, Analytical Chemistry 77 (2005) 878–885.
46 Amanulla Mohammed Fayaz, K. Balaji, M. Girilal, R. Yadav, P. T. Kalaichelvan, R. Venketesan, Biogenic synthesis of silver nanoparticles and their synergistic effect with antibiotics: a study against gram-positive and gram-negative bacteria, Nanomedicine: Nanotechnology, Biology and Medicine 6 (2010) 103-109.
47 V. K. Gupta, A. Mittal, D. Jhare, J. Mittal, Batch and bulk removal of hazardous colouring agent Rose Bengal by adsorption techniques using bottom ash as adsorbent, RSC Adv. 2 (2012) 8381-8389.
48 F. A. Ansari, M. Alam, Parthenium hysterophorous Weed: Novel adsorbent for the removal of pesticides mixture from aqueous solution, Indian J. Ana. Resea. 4 (2014) 439-442.
49 H. El Bakouri, J. Usero, J. Morillo, R. Rojas, A. Ouassini, Drin pesticides removal from aqueous solutions using acid-treated date stones, Biores. Tech. 100 (2009) 2676-2684.
50 H. El Bakouri, J. Usero, J. Morillo, A. Ouassini, Adsorptive features of acid-treated olive stones for drin pesticides: equilibrium, kinetic and thermodynamic modeling studies, Biores. Tech. 100 (2009) 4147-4155.
2 Arthur R. Gregory , J. Elliott, P. Kluge, Ames testing of direct black 38 parallels carcinogenicity testing, J. of app. Psycho. 1 (1981) 308-313.
3 Rajeshwari Sivaraj, C. Namasivayam, K. Kadirvelu, Orange peel as an adsorbent in the removal of Acid violet 17 (acid dye) from aqueous solutions, Waste Management 21 (2001) 105-110.
4 Kuo-Cheng Chen, J. Wu, C. Huang, Y. Liang, S. J. Hwang, Decolorization of azo dye using PVA-immobilized microorganisms, J. of Biotech. 101 (2003) 241-252.
5 Vinod K. Gupta, A. Mittal, R. Jain, M. Mathur, S. Sikarwar, Adsorption of Safranin-T from wastewater using waste materials— activated carbon and activated rice husks, J. of Col. and Interface Sci. 303 (2006) 80-86.
6 Vinod K. Gupta, R. Jain, S. Varshney, Removal of Reacto fix golden yellow 3 RFN from aqueous solution using wheat husk—An agricultural waste, J. of Hazar. Mat. 142 (2007) 443-448.
7 Vinod K. Gupta, I. Ali, V. K. Saini, Adsorption studies on the removal of Vertigo Blue 49 and Orange DNA13 from aqueous solutions using carbon slurry developed from a waste material, J. of Col. and Interface Sci. 315 (2007) 87-93.
8 V. K. Gupta, A. Mittal, V. Gajbe, J. Mittal, Adsorption of basic fuchsin using waste materials—bottom ash and deoiled soya—as adsorbents, J.of Col. and Interface Sci. 319 (2008) 30-39.
9 N. P. Cheremisinoff, Handbook of Water and Wastewater Treatment Technologies, Butterworth-Heinemann, Boston, 2002.
10 O. Marmagne, C. Coste, Color removal from textile plant effluents, Am. Dyestuff Rep. 85 (1996) 15–20.
11 Shi, B.Y., Li, G.H., Wang, D.S., Feng, C.H., Tang, H.X., Removal of direct dyes by coagulation: the performance of preformed polymeric aluminum species. J. Hazard. Mater. 143 (2007) 567–574.
12 Wang, M., Li, H., Wu, J., Huo, Y., Guo, G., Cao, F., Flocculant for purification of printing and dyeing wastewater. Univ Shanghai Normal 2006.
13 Zhou, Y., Liang, Z., Wang, Y., Decolorization and COD removal of secondary yeast wastewater effluents by coagulation using aluminium sulphate, Desalination 225 (2008) 301–311.
14 Gupta, V.K., Jain, R., Varshney, S., Electrochemical removal of the hazardousdye Reactofix Red 3 BFN from industrial effluents. J. Colloid Interface Sci. 312, 2007, 292–296
15 Lin, S.H., Peng, C.F., Treatment of textile wastewater by electrochemical method, Water Res. 28 (1994) 277–282.
16 V. K. Gupta, A. Mittal, V. Gajbe, Adsorption and desorption studies of a water soluble dye, Quinoline Yellow, using waste materials, J. of Col. and Interface Sci. 284 (2005) 89-98.
17 Bansal, R.C., Goyal, M., Activated Carbon Adsorption, Taylor & Francis Group, Boca Raton, 2005.
18 Danis, T.G., Albanis, T.A., Petrakis, D.E., Pomonis, P.J., Removal of chlorinated phenols from aqueous solutions by adsorption on alumina pillared clays and mesoporous alumina aluminum phosphates, Water Res. 32 (1998) 295–302.
19 Freeman, H.M., Standard Handbook of Hazardous Waste Treatment and Disposal, second ed. McGraw-Hill, New York, 1989.
20 K. Imamura, E. Ikeda, T. Nagayasu, T. Sakiyama, K. Nakanishi, Adsorption behavior of methylene blue and its congeners on a stainless steel surface, J. Colloid Interface Sci. 245 (2002) 50–57.
21 A. I. Liapis, Fundamentals of Adsorption. Engineering Foundation, New York, 1987.
22 C. L. Mantell, In: Adsorption, second ed. McGraw-Hill Book Company, Inc., New York, 1951.
23 J. S. Mattson, H.B.J. Mark, Activated Carbon Surface Chemistry and Adsorption from Solution. Marcel Dekker, Inc., New York, 1971.
24 M. Pirbazari, B. N. Badriyha, R. J. Miltner, GAC adsorber design for removal of chlorinated pesticides, J. Environ. Eng. ASCE 117 (1991) 80–100.
25 F. Quignon, F. Thomas, C. Gantzer, A. Huyard, L. Schwartzbrod, Virus adsorption in a complex system: an experimentally designed study, Water Res. 32 (1998) 1222–1230.
26 Weber Jr., W.J., Hopkins, C.B., Bloom Jr., R., Physicochemical treatment of wastewater, J. Water Pollut. Control Fed. 42 (1970) 83–89.
27 Palaniselvam Kuppusamy, M. M. Yusoff, G. P. Maniam, N. Govindan, Biosynthesis of metallic nanoparticles using plant derivatives and their new avenues in pharmacological applications – An updated report, Saudi Pharmaceutical Journal 24 (2016) 473–484.
28 Dapeng Chen, X. Qiao, X. Qiu, J. Chen, Synthesis and electrical properties of uniform silver nanoparticles for electronic applications, J. Mate. Sci. 44 (2009) 1076–1081.
29 Hongbo Wang, Q. Wei, X. Wang, W. Gao, X. Zhao, Antibacterial properties of PLA nonwoven medical dressings coated with nanostructured silver, Fibers and Polymers 9(2008) 556–560.
30 Lee Kim, K. Jun, W. S. Sung, S. Moon, J. Choi, J. G. Kim ,Antifungal Effect of Silver Nanoparticles on Dermatophytes and Dong Gun, J. Microbiol. Biotechnol. 18 (2008) 1482–1484.
31 H.J. Lee, S.Y. Yeo, S.H. Jeong, Antibacterial effect of nanosized silver colloidal solution on textile fabrics, J. Mater. Sci. 38 (2003) 2199-2204.
32 G. Lakshmanan, A. Sathiyaseelan, P. T. Kalaichelvan, K. Murugesan, Plant-mediated synthesis of silver nanoparticles using fruit extract of Cleome viscosa L.: Assessment of their antibacterial and anticancer Activity, Karbala International J. of Modern Sci. 4 (2018) 61-68.
33 V.V. Makarov, A.J. Love, O.V. Sinitsyna, S.S. Makarova, I.V. Yaminsky, M.E. Taliansky, N.O. Kalinina, Green nanotechnologies: synthesis of metal nanoparticles using plants, Acta Naturae 6 (1) (2014) 35-44.
34 Siavash Iravani, Green synthesis of metal nanoparticles using plants, Green Chem. 13 (2011) 2638-2650.
35 N. Cotolan, M. Rak, M. Bele, A. Cör, L.M. Muresan, and I. Milošev, “Sol-gel synthesis, characterization and properties of TiO2 and Ag-TiO2 coatings on titanium substrate,” Surf. & Coatings Technol., 307 (2016) 790–799.
36 C. Gutierrez-Wing, R. Esparza, C. Vargas-Hernandez, M.E.F. Garciaand M. Jose- Yacaman, “Microwave-assisted synthesis of goldnanoparticles self-assembled into self-supported superstructures,” Nanoscale 4 (2012) 2281–2287.
37 M.H. Magnusson, K. Deppert, J.O. Malm, J.O. Bovin, and L. Samuelson, “Size selected gold nanoparticles by aerosol technology,” Nanostruct. Mater., 12 (1999) 45-48.
38 J. Zhu, J. Shi, Y. Pan, X. Liu, and L. Zhou, “Synthesis of uniform silver nanoparticles by a microwave method in polyethylene glycol with the assistant of polyvinyl pyrrolidone,” J. Nat. Sci., 18 (2013) 530–534.
39 Thomas R, Nair AP, Kr S, Mathew J, Ek R. Antibacterial activity and synergistic effect of biosynthesized AgNPs with antibiotics against multidrug-resistant biofilm-forming coagulase-negative staphylococci isolated from clinical samples, Appl Biochem Biotechnol 173 (2014) 449-60.
40 Kumar PPNV, Pammi SVN, Kollu P, Satyanarayana KVV, Shameem U. Green synthesis and characterization of silver nanoparticles using Boerhaavia diffusa plant extract and their antibacterial activity. Ind Crops Prod 52 (2014) 562-6.
41 Matthew M. Zuckerman, Alan H. Molof and Walter J. Weber, High Quality Reuse Water by Chemical-Physical Wastewater Treatment [with Discussion] Jr. Journal (Water Pollution Control Federation) 42 (1970) 437-463.
42 M. G. Guzman, J. Dille, S. Godet, Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity. Int J Chem Biomol Eng 2 (2009) 104-11.
43 X. Fei, M. Jia, X. Du, Y. Yang, R. Zhang, Z. Shao, X. Zhao, X. Chen, Green synthesis of silk fibroin-silver nanoparticle composites with effective antibacterial and biofilm-disrupting properties, Biomacromolecules 14 (2013) 4483–4488.
44 Ales Panacek, M. Kolar, R. Vecerova, R. Prucek, J. Soukupova, V. Krystof, P. Hamal, R. Zboril, L. Kvitek, Antifungal activity of silver nanoparticles against Candida spp., Biomaterials 30 (2009) 6333-6340.
45 Christoph Seger, M. Godejohann, L. Tseng, M. Spraul, A. Girtler, S. Sturm, H. Stuppner, LC-DAD-MS/SPE-NMR Hyphenation. A Tool for the Analysis of harmaceutically Used Plant Extracts: Identification of Isobaric Iridoid Glycoside Regioisomers from Harpagophytum procumbens, Analytical Chemistry 77 (2005) 878–885.
46 Amanulla Mohammed Fayaz, K. Balaji, M. Girilal, R. Yadav, P. T. Kalaichelvan, R. Venketesan, Biogenic synthesis of silver nanoparticles and their synergistic effect with antibiotics: a study against gram-positive and gram-negative bacteria, Nanomedicine: Nanotechnology, Biology and Medicine 6 (2010) 103-109.
47 V. K. Gupta, A. Mittal, D. Jhare, J. Mittal, Batch and bulk removal of hazardous colouring agent Rose Bengal by adsorption techniques using bottom ash as adsorbent, RSC Adv. 2 (2012) 8381-8389.
48 F. A. Ansari, M. Alam, Parthenium hysterophorous Weed: Novel adsorbent for the removal of pesticides mixture from aqueous solution, Indian J. Ana. Resea. 4 (2014) 439-442.
49 H. El Bakouri, J. Usero, J. Morillo, R. Rojas, A. Ouassini, Drin pesticides removal from aqueous solutions using acid-treated date stones, Biores. Tech. 100 (2009) 2676-2684.
50 H. El Bakouri, J. Usero, J. Morillo, A. Ouassini, Adsorptive features of acid-treated olive stones for drin pesticides: equilibrium, kinetic and thermodynamic modeling studies, Biores. Tech. 100 (2009) 4147-4155.